Thursday, February 7, 2008

Leather production processes

The leather manufacturing process is divided into 3 fundamental sub-processes: preparatory stages, tanning and crusting. All true leathers will undergo these sub-processes. A further sub-process, surface coating can be added into the leather process sequence but not all leathers receive surface treatment. It's difficult to have a list of operations that all leathers must undergo, as there are so many types of leather.

The preparatory stages are when the hide/skin is prepared for tanning. Preparatory stages may include: preservation, soaking, liming, unhairing, fleshing, splitting, reliming, deliming, bating, degreasing, frizing, bleaching, pickling and depickling.

Tanning is the process converts the protein of the raw hide or skin into a stable material which will not putrefy and is suitable for a wide variety of end applications. The principal difference between raw hides and tanned hides is that raw hides dry out to form a hard inflexible material that when re-wetted (or wetted back) putrefy, whilst tanned material dries out to a flexible form that does not become putrid when wetted back. There is a large number of different tanning methods and materials that can be used, the choice is ultimately dependent on the end application of the leather. The most commonly used tanning material is chromium, which leaves the leather once tanned a pale blue colour (due to the chromium), this product is commonly called “wet blue”. The hides once they have finished pickling will typically be between pH of 2.8-3.2. At this point the hides would be loaded in a drum and immersed in a float containing the tanning liquor. The hides are allowed to soak (while the drum slowly rotates about its axle) and the tanning liquor slowly penetrates through the full substance of the hide. Regular checks will be made to see the penetration by cutting the cross section of a hide and observing the degree of penetration. Once a good even degree of penetration exists, the pH of the float is slowly raised in a process called basification. This basification process fixes the tanning material to the leather and the more tanning material fixed the higher the hydrothermal stability and increased shrinkage temperature resistance of the leather. The pH of the leather when chrome tanned would typically finish somewhere between 3.8-4.2.

Crusting is when the hide/skin is thinned, retanned and lubricated. Often a coloring operation is included in the crusting sub-process. The chemicals added during crusting have to be fixed in place. The culmination of the crusting sub-process is the drying and softening operations. Crusting may include the following operations: wetting back, sammying, splitting, shaving, rechroming neutralisation, retanning, dyeing, fatliquoring, filling, stuffing, stripping, whitening, fixation, setting, drying, conditioning, milling, staking and buffing.

For some leathers a surface coating is applied. Tanners refer to this as finishing. Finishing operations may include: oiling, brushing, padding, impregnation, buffing, spraying, roller coating, curtain coating, polishing, plating, embossing, ironing, ironing/combing(for hair-on)and glazing.

Rawhide

Rawhide is a hide or animal skin that has not been exposed to tanning and thus is much lighter in color than treated animal hides (leather). The term hide refers to the covering of a large adult animal such as a cow, buffalo, horse etc. The term skin refers to the covering of a small animal, such as a sheep, goat, pig etc or the young of a large animal.

The skin from buffalo, deer, elk or cattle from which most rawhide originates is devoid of all fur, meat and fat. The resulting material is often only semi-pliable and permeable to light.

Tanning

Tanning is the process of converting putrescible skin into non-putrescible leather, usually with tannin, an acidic chemical compound that prevents decomposition and often imparts color. Tanning leather involves a process which permanently alters the protein structure of skin so that it can not ever return to rawhide. Making rawhide does not require the use of tannin and is made simply by removing the flesh and then the hair by way of soaking in an aqueous solution (often called liming when using lime and water or bucking when using wood ash (lye) and water), then scraping over a beam with a somewhat dull knife, and then leaving to dry, usually stretched on a frame so that it dries flat. The two aforementioned solutions for removing the hair also act to clean the fiber network of the skin and therefore allow penetration and action of the tanning agent.

Leather

Leather is a material created through the tanning of hides and skins of animals, primarily cattlehide. The tanning process converts the putrescible skin into a durable, long-lasting and versatile natural material for various uses.

Leather is an important material with many uses. Together with wood, leather formed the basis of much ancient technology. The leather industry and the fur industry are distinct industries that are differentiated by the importance of their raw materials. In the leather industry the raw materials are by-products of the meat industry, with the meat having higher value than the skin. The fur industry uses raw materials that are higher in value than the meat and hence the meat is classified as a by-product. Taxidermy also makes use of the skin of animals, but generally the head and part of the back are used. Hides and skins are also used in the manufacture of glue and gelatin.